首页  >  科学研究  >  科研成果  >  正文
科研成果
张洪雷的论文在ChemSusChem刊出
发布时间:2017-09-08 17:38:11     发布者:yz     浏览次数:

标题:Highly Efficient Sulfonic/Carboxylic Dual-Acid Synergistic Catalysis for Esterification Enabled by Sulfur-Rich GrapheneOxide

作者:Honglei Zhang, Xiang Luo, Kaiqi Shi, Tao Wu, Feng He, Shoubin Zhou, George Z. Chen, and Chuang Peng

来源出版物:ChemSusChem卷:10 页码: 3352-3357 DOI:10.1002/cssc.201700950 出版年:2017

摘要:A new sulfonic/carboxylic dual-acid catalyst based on sulfur-rich graphene oxide (GO-S) was readily prepared and used as a highly efficient and reusable solid acid catalyst toward the esterification of oleic acid with methanol for biodiesel production. Higher yields of methyl oleate (98 %) and over 3 times higher turnover frequencies (TOFs) were observed for the GO-S dual-acid catalyst, compared to liquid sulfuric acid or other carbon-based solid acid catalysts. The “acidity” of sulfonic acid groups was enhanced by the addition of carboxylic acid groups as the combination of the two acids enhances their inherent activity by associative interaction.

文献类型:Article

语种:English

作者关键词: dual-acid catalyst;esterification;graphene oxide;heterogeneous catalysis;solid acid

通讯作者地址:Honglei Zhang; School of Resource and Environmental Sciences, Hubei International Scientific and Technological Cooperation Base, of Sustainable Resource and Energy, Wuhan University, Wuhan, P. R. China

Feng He;College of Environment, Zhejiang University of Technology, Hangzhou Zhejiang, P. R. China

电子邮件地址:honglei.zhang@whu.edu.cn;fenghe@zjut.edu.cn

地址:

[Honglei Zhang, Chuang Peng]School of Resource and Environmental Sciences, Hubei International Scientific and Technological Cooperation Base, of Sustainable Resource and Energy, Wuhan University, Wuhan, P. R. China

[Xiang Luo, Kaiqi Shi, Tao Wu]New Materials Institute, University of Nottingham Ningbo China, Ningbo, P. R. China

[Tao Wu]Municipal Key Laboratory of Clean Energy Conversion Technologies, University of Nottingham Ningbo, Ningbo, P. R. China

[Feng He]College of Environment, Zhejiang University of Technology, Hangzhou Zhejiang, P. R. China

[Shoubin Zhou]Huafu High Technology Energy Storage Co., Ltd, Yangzhou, Jiangsu, P. R. China

[George Z. Chen]Department of Chemical and Environmental Engineering, Advanced Materials Research Group, University of Nottingham, Nottingham, UK

[George Z. Chen]Department of Chemical and Environmental Engineering, Energy Engineering Research Group, Faculty of Science and Engineering, University of Nottingham Ningbo, Ningbo, P. R. China

研究方向:Chemistry; Science & Technology - Other Topics

ISSN:1864-5631

eISSN: 1864-564X

影响因子:7.226

信息服务
学院网站教师登录 学院办公电话 学校信息门户登录

版权所有 © bwin·必赢(中国)唯一官方网站
地址:湖北省武汉市珞喻路129号 邮编:430079 
电话:027-68778381,68778284,68778296 传真:027-68778893    邮箱:sres@whu.edu.cn