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博士生王志平的论文在INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH刊出
发布时间:2015-11-16 14:30:37     发布者:yz     浏览次数:

标题:Mass Transfer-Reaction Kinetics Study on Absorption of NO with Dual Oxidants (H2O2/S2O82-)作者:Wang, Zhiping; Wang, Zuwu

来源出版物:INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH 卷:54 期:41页:9905-9912 DOI:10.1021/acs.iecr.5b02162 出版年:OCT 21 2015

摘要:The mass transfer-reaction kinetics of NO absorption by dual oxidants (H2O2/S2O82-) was studied in a bubble column reactor. The comparison experiments in different systems showed that the combination of Na2S2O8 and H2O2 had significant synergistic effects on the rate of NO absorption. The effects of Na2S2O8 concentration, H2O2 concentration, NO concentration, pH, O-2 concentration, and gas flow rate on the rate of NO absorption were investigated. The rate of NO absorption increased with the increase in Na2S2O8 concentration, H2O2 concentration, and gas flow rate. The rate of NO absorption increased slightly with the increase in 02 concentration, whereas it increased linearly with the increase in NO concentration. At pH 11, the rate of NO absorption reached 1.31 X 10(-6) mol/m(2).s. The NO absorption by dual oxidants (H2O2/S2O82-) was pseudo-first-order with respect to the NO concentration. Moreover, a simple rate equation of NO absorption by H2O2/S2O82- was obtained. The results of the rate equation indicate that the calculated values are consistent with the experimental values.

入藏号:WOS:000363438500001

文献类型:Article

语种:English

扩展关键词:NITRIC-OXIDE; FLUE-GAS; SCRUBBING SOLUTION; SODIUM PERSULFATE; HYDROGEN-PEROXIDE; AQUEOUS-SOLUTIONS; OXIDATION; REMOVAL; SO2; CHEMISTRY

通讯作者地址:Wang, Zuwu; Wuhan Univ, Dept Environm Engn, Wuhan 430079, Peoples R China.

电子邮件地址:hjgcapc@163.com

地址:[Wang, Zhiping; Wang, Zuwu] Wuhan Univ, Dept Environm Engn, Wuhan 430079, Peoples R China.

研究方向:Engineering

ISSN:0888-5885

影响因子(2014):2.587

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